ABSTRACT
Indiscriminate disposal of waste from the oil industry has led to contamination of soils and water sources and toxic effects in the biota. Thus, this study aimed to assess barium (Ba) and lead (Pb) spatial variability in disposal sites for oil well drilling and prospecting wastes. The soil in the study area is classified as Red Latosol, and the area is located in Santa Maria do Oeste, Paraná State (Brazil). Barium and Pb spatial variabilities were determined using a 76-point sampling grid. The levels of metals were determined in soil samples collected at each sampling point, at the depth ranges of 0.0-0.3, 0.3-0.6, 0.6-0.9 and 0.9-1.2 m. Data were mapped using geostatistical interpolators for spatial dependence determination, modeling and validation of semivariograms, and respective interpolation. Thirty Ba and Pb high concentration samples were selected for leaching and solubilization assays. As semivariogram analysis showed spatial dependence, mapping by ordinary kriging was performed for both metals. The high levels found for both metals arose from well drilling activities, as no direct relationship was found between such levels with geology and genesis of the local rock. The concentrations of the metals were higher than the research values considering the Agricultural / AP-Max scenario, therefore, the study area was characterized as class 4 (contaminated). Although these metals have low solubility, i.e. low contamination risk to subsurface waters, they may pose contamination risks to water bodies by means of soil runoff.
Keywords:
Geostatistics; Heavy metal; Soil contamination
