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Microstructural and phase analysis of cemented carbide doped with rare-earths sintered via liquid phase

The principal aim of this work is the microstructural and phases characterization of the cemented carbide (WC/10Co) doped with rare-earths (La2O3 and CeO2). This cemented carbide is widely used as cutting tool. Several WC/10Co mixtures containing up to 3 wt % La2O3 and CeO2 of the cobalt phase were prepared. The mixed powders were uniaxially pressed at 200 MPa in a cylindrical matrix (phi = 10 mm). The compacts were sintered under vacuum at 1400ºC during 60 min. The relative density of the pieces was determined. The sintered pieces were submitted to X-ray diffraction and scanning electronic microscopy via secondary electron images. The results showed that, within the conditions studied, the addition of rare-earth elements influenced positively the densification of the WC/10Co cemented carbide during the sintering process. The sintered microstructure of pieces didn’t suffer significant modifications with the addition of the rare-earth elements studied.

Cemented carbide; rare-earth; microstructure; XRD


Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
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