Polymer models using the tight-binding Hamiltonian

The tight-binding model is a cornerstone of Condensed Matter Physics, describing in a simple way a wide range of phenomena, such as the band structure of materials and the electronic transport. In this paper, the referred model, written in the language of second quantization, is used to describe the density of states in organic polymers. Using the second quantization method the expressions for the hopping parameters emerge quite naturally. The infinite atomic chain, the benzene, cyclopentadiene and tyophene molecules are analyzed within the tight-binding model.

Keywords
Tight-binding; polymers; hopping; second quantization