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Flammability of polypropylene/organoclay nanocomposites

The flammabilities of nanocomposites made with three polypropylene grades (homo and copolymers) with 5 wt % of organoclay (Cloisite 20A), 5 or 15 wt % of maleated polypropylene as compatibilizer, and 0, 0.5 or 1 wt % of cis-13-docosenamide (Erucamide) as co-intercalant, were studied using the horizontal burning test UL94HB. Masterbatches prepared in an internal mixer were diluted in the polypropylene matrix using a corotating twin-screw extruder, with different screw configurations and operating at 240 or 480 rpm. Results indicate that the high burning rate of the composites was not affected by the processing conditions. For all formulations was observed a significant reduction in smoke release, lack of dripping and the formation of a char surface layer, that protected the core of the samples.

Polypropylene; nanocomposites; processing; flammability


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