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Effect of loading level and clay purification on the structure and water vapor permeability of LLDPE/bentonite nanocomposites

This work is concerned with the preparation, characterization and measurement of water vapor permeability of LLDPE/bentonite nanocomposite films, containing 1% and 2% of natural, purified, and organophilized clay. FTIR and XRD techniques were used to characterize the clay and the composites. The results pointed to an effective clay purification procedure (removal of organic matter). Mostly intercalated nanocomposites were obtained in all cases. The addition of clay significantly increased the permeability of the films to water vapor. However, purification and/or organophilization of the clay, as well as loading level, were found to have little effect on the permeability.

LLDPE; bentonite; nanocomposites; films; permeability


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