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Determination of activation energy in polymeric hydrogels using thermogravimetric analysis

Polyelectrolyte hydrogels formed by chitosan/xanthan (QX) and chitosan/xanthan/collagen (QXC) were prepared and thermogravimetric curves at different heating rates were obtained, with the aim of determining kinetic parameters using the Flynn-Wall method. The calculated activation energy was 3.44 kJ.mol-1 (QX ) and 14.84 kJ.mol-1 (QXC), suggesting stronger interactions in QXC hydrogel structure than in the QX hydrogel, probably due to the presence of carboxyl groups of collagen molecules.

Hydrogels; activation energy; thermogravimetry; biopolymers


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