Plasma Electrolytic Nitrocarburizing of SAE 1045: Electro-chemical Slurry Erosion Wear Analysis

Nitrocarburized coating by plasma electrolytic saturation, PEN/C coatings, have been proposed to increase the corrosion and wear resistance of steel by using a process of low-temperature hydrostatic plasma. The objective of this work is to analyse the wear and corrosion resistance of PEN/C coatings on SAE 1045 steel, using the electrochemical slurry erosion wear test (ESEWT). This test allows the evaluation of the simultaneous effect of erosion wear and electrochemical behaviour on this coating. Thus, it was possible to evaluate the erosive and corrosive effect and the synergy of these phenomena on the PEN/C coated SAE 1045 mass loss rates. ESEWT tests were performed at different times and under different electrochemical conditions: under cathodic protection and open circuit potential (OCP). The PEN/C coating increased the corrosion resistance of SAE 1045. Synergy between the erosive wear and corrosion was the main factor in the mass loss rates of both analysed systems. The synergistic mechanism of the substrate occurred by removing the corrosion product and by activating the surface generated by the erosive process of the particles. The synergistic mechanism of the PEN/C coating occurred with the removal of inherent surface irregularities through the erosive process, combined with localized corrosion.

Keywords:
slurry erosion wear ; corrosion ; plasma electrolytic saturation ; steel