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Short Report • J. Braz. Chem. Soc. 12 (5) • Oct 2001 • https://doi.org/10.1590/S0103-50532001000500012   copy

The reaction of 1-tetralones with thallium trinitrate supported on clay: ring contraction vs alpha-oxidation

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The reaction of a series of 1-tetralones with thallium trinitrate supported on Montmorillonite K-10 clay led to products of ring contraction (methyl indan-1-carboxylates) and/or alpha-oxidation (2-methoxy-1-tetralones), in variable yields.

thallium trinitrate; Montmorillonite K-10; ring contraction; alpha-oxidation; indans

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