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Fast and simultaneous determination of Pb2+ and Cu2+ in water samples using a solid paraffin-based carbon paste electrode chemically modified with 2-aminothiazole-silica-gel

A solid paraffin-based carbon paste electrode modified with 2-aminothiazole functionalized silica-gel was used for simultaneous quantification of Pb2+ and Cu2+ in water samples by anodic stripping voltammetry. The present method uses short preconcentration time (180 s), which allowed reliable and simultaneous quantification of Pb2+ and Cu2+ in a very fast way. Detection limits of 7.3 and 90 nmol L-1 were obtained for Pb2+ and Cu2+, respectively. These values are below their maximum concentrations allowed in drinking water by Brazilian legislation, indicating that the proposed method is useful to monitoring Pb2+ and Cu2+ in water samples. Recovery studies were performed in four spiked water samples and the results shown recovery percentages close to 100% for all analyzed samples, demonstrating the good accuracy of the proposed method

anodic stripping voltammetry; carbon paste electrode; 2 -aminothiazole-functionalized silica gel; lead and copper determination; water samples


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