Removal of iron ions from water contaminated with acid mine drainage by geopolymer derived from rice husk ash and ceramic residue

Wesler, Sabrina; Brida, Isabel Conceição de; Geremias, Reginaldo; Menezes, Carlyle Torres Bezerra de; Pineda-Vasquez, Tatiana

doi:10.1590/S1413-415220200123

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Artigo Técnico • Eng. Sanit. Ambient. 26 (6) • Nov-Dec 2021 • https://doi.org/10.1590/S1413-415220200123 copy

Removal of iron ions from water contaminated with acid mine drainage by geopolymer derived from rice husk ash and ceramic residue

Authorship SCIMAGO INSTITUTIONS RANKINGS

Abstract

Acid mine drainage is a worldwide problem and is characterized by high acidity, low pH and expressive concentration of heavy metals, such as iron, Mn and many others, directly affecting water sources and rivers. In search of an alternative that could efficiently and economically improve the levels of acidity and water iron impacted by acid mine drainage, a geopolymeric adsorbent based on residual materials was developed: from the ceramic industry and rice processing (rice husk ash). In this work, it was evaluated the efficiency of the geopolymer in removing iron ions in water contaminated with acid mine drainage. Aspects of adsorbent dosage, temperature effect, initial iron concentrations, kinetics and thermodynamic parameters of the adsorption process were evaluated. The percentage of iron removed was 92.76%, at a temperature of 25 °C, for 20 min, with an adsorbent concentration of 4 g L^-1, with the maximum capacity for adsorption of iron by the geopolymer being 7.18 mg.g^-1. The main mechanism of adsorption occurred due to chemisorption, which follows the kinetic model of pseudo-second order. Geopolymer appears potentially useful an efficient alternative in the treatment of water contaminated with acid mine drainage.

Keywords:
acid mine drainage; adsorption of iron; waste; geopolymer

Referência	Adsorvente	Amostra	Espécie removida	pH	Capacidade de adsorção (q_e)	Eficiência de remoção (%)
*Al-Harahsheh, M. S et al. (2015)*AL-HARAHSHEH, M. S.; AL ZBOON, K.; AL-MAKHADMEH, L.; HARARAH, M.; MAHASNEH, M. Fly ash based geopolymer for heavy metal removal: a case study on copper removal. Journal of Environmental Chemical Engineering, v. 3, n. 3, p. 1669-1677, 2015. https://doi.org/10.1016/j.jece.2015.06.005 https://doi.org/10.1016/j.jece.2015.06.0...	Geopolímero à base de cinzas volantes	Solução aquosa	Cu²⁺	6,0	152,3 mg.g^-1
*Liu, Y. et al.* (2016)**LIU, Y.; YAN, C.; ZHANG, Z.; WANG, H.; ZHOU, S.; ZHOU, W. A comparative study on fly ash, geopolymer and faujasite block for Pb removal from aqueous solution. Fuel, v. 185, p. 181-189, 2016. https://doi.org/10.1016/j.fuel.2016.07.116 https://doi.org/10.1016/j.fuel.2016.07.1...	Geopolímero à base de cinzas volantes, cinzas volantes e bloco de faujasita	Solução aquosa	Pb²⁺	3,0	Geopolímero à base de cinzas volantes = 118,6 mg.g^-1 Cinzas volantes = 49,8 mg.g^-1 Bloco de faujasita = 143,3 mg.g^-1
*Luukkonen et al.* (2016)**LUUKKONEN, T.; RUNTTI, H.; NISKANEN, M.; TOLONEN, E.-T.; SARKKINEN, M.; KEMPPAINEN, K.; LASSI, U. Simultaneous removal of Ni(II), As(III), and Sb(III) from spiked mine effluent with metakaolin and blast-furnace-slag geopolymers. Journal of environmental management, v. 166, p. 579-588, 2016. https://doi.org/10.1016/j.jenvman.2015.11.007 https://doi.org/10.1016/j.jenvman.2015.1...	Geopolímero de escória de alto forno	DAM	Ni²⁺ As³⁺ Sb³⁺	7,0-8,0	Ni = 4,42 mg.g^-1 As = 0,52 mg.g^-1 Sb = 0,34 mg.g^-1	90–100%
Kara, Yilmazer e Akar (2017)KARA, I.; YILMAZER, D.; AKAR, S. T. Metakaolin based geopolymer as an effective adsorbent for adsorption of zinc (ii) and nickel (ii) ions from aqueous solutions. Applied Clay Science, v. 139, p. 54-63, 2017. https://doi.org/10.1016/j.clay.2017.01.008 https://doi.org/10.1016/j.clay.2017.01.0...	Geopolímero à base de metacaulim	Solução aquosa	Zn²⁺ Ni²⁺	Zn = 6,39 Ni = 7,25	Zn = 1,14 10⁻³ mol.g^-1 Ni = 7,26 10⁻⁴ mol.g^-1
Jeremias, T.; Pineda-Vásques, T.; Lobo-Recio, M. (2018)JEREMIAS, T.; PINEDA-VÁSQUES, T.; LOBO-RECIO, M. Utilização de cinza da casca do arroz como biossorvente na remediação de águas fluviais impactadas por drenagem ácida mineral. In: Simpósio de Integração Científica e Tecnológica do Sul Catarinense – 7° SICT, Araranguá, 2018. Anais […]. Araranguá: Instituto Federal de Santa Catarina, 2018. Disponível em: http://eventoscientificos.ifsc.edu.br/index.php/sictsul/7-sict-sul/paper/view/2496. Acesso em: 20 out. 2019. http://eventoscientificos.ifsc.edu.br/in...	Cinza da casca de arroz	Água fluvial com DAM	Íons Fe, Al e Mn	2,88–3,56	Aumento ~ 45% da concentração de Mn na solução	Fe (> 98%) Al (~ 35%)
Fontana, I.; Michael Peterson, M.; e Cechinel, M. (2018)FONTANA, I.; PETERSON, M.; CECHINEL, M. Application of brewing waste as biosorbent for the removal of metallic ions present in groundwater and surface waters from coal regions. Journal of Environmental Chemical Engineering, v. 6, n. 1, p. 660-670, 2018. http://doi.org/10.1016/j.jece.2018.01.005 http://doi.org/10.1016/j.jece.2018.01.00...	Resíduo da cerveja	Solução aquosa com DAM	Íons Fe e Mn	5,3	Fe = 4 ± 1 mg.g^-1 Mn = 0,96 ± 0,06 mg.g^-1	Fe = 87% Mn = 71%
*Núñez-Gómez et al.* (2019)**NÚÑEZ-GÓMEZ, D.; RODRIGUES C.; LAPOLLI, F.; LOBO-RECIO, M. A. Adsorption of heavy metals from coal acid mine drainage by shrimp shell waste: isotherm and continuous-flow studies. Journal of Environmental Chemical Engineering, v. 7, n. 1, p. 102787, 2019. http://doi.org/10.1016/j.jece.2018.11.032 http://doi.org/10.1016/j.jece.2018.11.03...	Casca de camarão in natura	DAM	Íons Fe e Mn	3,49–6,77	Fe = 17, 43 mg.g^-1 Mn = 3, 87 mg.g^-1	Fe (até 90%) Mn (até 88%)
*Maleki et al.* (2019)**MALEKI, A.; HAJIZADEH, Z.; SHARIFI, V.; EMDADI, Z. A green, porous and eco-friendly magnetic geopolymer adsorbent for heavy metals removal from aqueous solutions. Journal of Cleaner Production, v. 215, p. 1233-1245, 2019. https://doi.org/10.1016/j.jclepro.2019.01.084 https://doi.org/10.1016/j.jclepro.2019.0...	Argila bentonita	Águas residuais industriais	Metais pesados como Cu, Pb, Ni, Cd e Hg	7,0		Cu (99%) Pb (99%) Ni (92%) Cd (96%) Hg (92%)
*Yan et al.* (2019)**YAN, S.; HE, P.; JIA, D.; WANG, Q.; LIU, J.; YANG, J.; HUANG, Y. A green and low-cost hollow gangue microsphere/geopolymer adsorbent for the effective removal of heavy metals from wastewaters. Journal of Environmental Management, v. 246, p. 174-183, 2019. http://doi.org/10.1016/j.jenvman.2019.05.120 http://doi.org/10.1016/j.jenvman.2019.05...	Microesferas ocas de ganga	Solução aquosa	Cu²⁺ Cd²⁺ Zn²⁺ Pb²⁺	2,0–30	Cu²⁺ = 13,38 mg.g^-1 Cd²⁺ = 10,83 mg.g^-1 Zn²⁺ = 6,48 mg.g^-1 Pb²⁺ = 61,4 mg.g^-1
*Ryu et al.* (2020)**RYU, S.; NAIDU, G.; MOON, H.; VIGNESWARAN, S. Selective copper recovery by membrane distillation and adsorption system from synthetic acid mine drainage. Chemosphere, v. 260, p. 127528, 2020. https://doi.org/10.1016/j.chemosphere.2020.127528 https://doi.org/10.1016/j.chemosphere.20...	Sílica mesoporosa modificada com Mn e enxerto de amina	DAM sintética	Cu²⁺	2,0–2,2 – 5,0–5,2	24,53 mg.g^-1 para DAM tratada com KOH e 18,11 mg.g^-1 para DAM tratada com NaOH
*Larazatou C. et al.* (2020)**LARAZATOU, C.; PANAGIOTARAS, D.; PANAGOPOULOS, G.; POSPÍŠIL, M.; PAPOULIS, D. Ca treated Palygorskite and Halloysite clay minerals for Ferrous Iron (Fe+2) removal from water systems. Environmental Technology & Innovation, v. 19, p. 10096, 2020. http://doi.org/10.1016/j.eti.2020.100961 http://doi.org/10.1016/j.eti.2020.100961...	Fibras de palygorskita e nanotubos de haloisita	Solução aquosa	Fe²⁺	Ca-Pal (4,0–6,0) Ca-Hall (pH > 8)		Ca-Pal = 99,8% Ca-Hall = 91,2%
*Ngueagni et al.* (2020)**NGUEAGNI, P.; WOUMFO, E. D.; KUMAR, P. S.; SIÉWÉ, M.; VIEILLARD, J.; BRUN, N.; NKUIGUE, P. F. Adsorption of Cu(II) ions by modified horn core: effect of temperature on adsorbent preparation and extended application in river water. Journal of molecular liquids, v. 298, p. 112023, 2020. http://doi.org/10.1016/j.molliq.2019.112023 http://doi.org/10.1016/j.molliq.2019.112...	Núcleo do chifre do boi	Água fluvial com metais	Cu²⁺	4,12–4,64	99,98 mg.g^-1
*He et al.* (2020)**HE, X.; YAO, B.; XIA, Y.; HUANG, H.; GAN, Y.; ZHANG, W. Coal fly ash derived zeolite for highly efficient removal of Ni2+ inwaste water. Powder technology, v. 367, p. 40-46, 2020. https://doi.org/10.1016/j.powtec.2019.11.037 https://doi.org/10.1016/j.powtec.2019.11...	Zeólita tipo A derivada de cinzas volantes de carvão	Águas residuais industriais	Ni²⁺	7,0	47,0 mg.g^-1	94%
*Sahoo et al.* (2020)**SAHOO, H.; SENAPATI, D.; THAKUR, I. S.; NAIK, U. C. Integrated bacteria-algal bioreactor for removal of toxic metals in acid mine drainage from iron ore mines. Bioresource Technology Reports, v. 11, p. 100422, 2020. http://doi.org/10.1016/j.biteb.2020.100422 http://doi.org/10.1016/j.biteb.2020.1004...	Bactérias e algas	DAM	Íons Fe, Al, Mn, Cu, Ti, Si e S	4,3–7,0		95–99%
*Liu et al.* (2021)**LIU, J. REN, S.; CAO, J.; TSANG, D. C. W.; BEIYUAN, J.; PENG, Y.; WANG, J. Highly efficient removal of thallium in wastewater by MnFe2O4-biochar composite. Journal of Hazardous Materials, v. 401, p. 123311, 2021. http://doi.org/10.1016/j.jhazmat.2020.123311 http://doi.org/10.1016/j.jhazmat.2020.12...	MnFe₂O₄ –Biocarvão	Águas residuais industriais	TI (l)	6,0	170,55 mg.g^-1	49,61%

Composição (m%)
Al₂O₃	CaO	Fe₂O₃	K₂O	MgO	MnO	Na₂O	P₂O₅	SiO₂	TiO₂	PI^* * PI: perda por ignição em 960°C.
14,23	3,71	0,37	1,10	1,59	0,05	24,22	0,38	49,48	0,18	4,68

Modelo de pseudoprimeira ordem			Modelo de pseudos segunda ordem
q_e (mg g^-1)	K₁(min^-1)	R²	q_e (mg g^-1)	K₂ (g.mg^-1min^-1)	R²
7,19	0,0004	0,9286	7,03	0,82	0,99997

Isoterma de Langmuir
	298 K	303 K	308 K
q_m (mg.g^-1)	1,175	1,563	1,086
K_L (L.mg^-1)	0,425	0,552	1,855
R_L	0,07	0,06	0,02
R²	0,9986	0,9745	0,9638
Isoterma de Freundlich
K_f (L.mg^-1)	93,41	24,12	3,217
1/n_F	2,5387	1,5426	0,9449
R²	0,9919	0,8296	0,9615

Temperatura (K)	ΔG (J.mol^-1)	ΔH (KJ.mol^-1)	ΔS (J.(mol.K)^-1)
298	-34911,6	112,04	491,78
303	-36156,0
308	-39856,5

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[1] * Autor correspondente: latatiss@gmail.com