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Stable isotopes and beverage production: where does the carbon we drink come from?

We used the carbon isotopic composition (delta13C) to determine the botanical origin (whether C3 or C4) of coffee, wine, beer and vodka samples from different brands and origins commercialized in Brazil. Only one coffee sample showed a delta13C typical of a mixture with C4 plants (delta13C -16.2‰). The Brazilian wine samples varied from delta13C -25.1 to -18.6‰, indicating the presence of carbon from C4 plants in samples with greater values, while the imported wine showed delta13C characteristic of C3 plants (-27.1 and -26.3‰). Imported vodka also showed delta13C typical of C3 plants (-26.4 and -23.9‰), while Brazilian counterparts were typically made from C4 plants (-12.8 to -11.8‰), except for one sample (23,1‰). Most of the imported beers showed more negative d13C (-27.3 to -20.7‰) than did the Brazilian beers (-25.9 to -18.4‰). These results demonstrate the method's efficiency for tracing the carbon origin and determining the extent of blending in beverages.

stable isotope; carbon; coffee; wine; vodka; beer


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