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APPLICATION OF A SURFACE-RENEWAL MODEL TO PERMEATE-FLUX DATA FOR CONSTANTPRESSURE CROSS-FLOW MICROFILTRATION WITH DEAN VORTICES

Abstract

The introduction of flow instabilities into a microfiltration process can dramatically change several elements such as the surface-renewal rate, permeate flux, specific cake resistance, and cake buildup on the membrane in a positive way. A recently developed surface-renewal model for constant-pressure, cross-flow microfiltration (Hasan et al., 2013Hasan, A., Peluso, C. R., Hull, T. S., Fieschko, J. and Chatterjee, S. G., A surface-renewal model of cross-flow microfiltration. Brazilian Journal of Chemical Engineering, 30, 167-186 (2013).) is applied to the permeate-flux data reported by Mallubhotla and Belfort (1997)Mallubhotla, H. and Belfort, G., Flux enhancement during Dean vortex microfiltration. 8. Further diagnostics. J. Membrane Sci., 125, 75-91 (1997)., one set of which included flow instabilities (Dean vortices) while the other set did not. The surface-renewal model has two forms - the complete model and an approximate model. For the complete model, the introduction of vortices leads to a 53% increase in the surface-renewal rate, which increases the limiting (i.e., steady-state) permeate flux by 30%, decreases the specific cake resistance by 14.5% and decreases the limiting cake mass by 15.5% compared to operation without vortices. For the approximate model, a 50% increase in the value of surface renewal rate is shown due to vortices, which increases the limiting permeate flux by 30%, decreases the specific cake resistance by 10.5% and decreases the limiting cake mass by 13.7%. The cake-filtration version of the critical-flux model of microfiltration (Field et al., 1995Field, R. W., Wu, D., Howell, J. A. and Gupta, B. B., Critical flux concept for microfiltration fouling. J. Membrane Sci., 100, 259-272 (1995).) is also compared against the experimental permeate-flux data of Mallubhotla and Belfort (1997)Mallubhotla, H. and Belfort, G., Flux enhancement during Dean vortex microfiltration. 8. Further diagnostics. J. Membrane Sci., 125, 75-91 (1997).. Although this model can represent the data, the quality of its fit is inferior compared to that of the surface-renewal model.

Keywords
Critical-flux model; Dean vortices; Microfiltration; Surface-renewal model

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